| |
|
Physical
Data
|
|
Mean coefficient
of linear expansion 20/300
acc. to ISO 3585
|
3.3
10-6 K-1
|
|
Transformation
temperature Tg
|
525°C
|
Temperature
fixed points at viscosity in
dPa s:
|
|
|
1013
upper annealing point
|
560°C
|
|
107.6
softening point
|
825°C
|
|
104
working point
|
1260°C
|
|
Maximum
short-time working temperature
|
500°C
|
|
Density
p
|
2.23g
cm-3
|
|
Modulus
of elasticity E
|
64
103 N mm-2
|
Poisson's
ratio
|
0.20
|
Thermal
conductivity w
at 90°C
|
1.2 W
m-1K-1
|
Temperature
for the specific electrical resistance of 108
cm (DIN 52326) tk 100
|
250°C
|
Logarithm
of the electric volume resistance (
cm)
|
|
|
at 250°C
|
8
|
|
at 350°C
|
6.5
|
|
Dielectric
properties (1 MHz, 25°C)
|
|
Dielectric
figure
|
4.6
|
Dielectric
loss factor tan 
|
37-10-4
|
Refractive
index ( = 587.6 nm)
nd
|
1.473
|
|
Stress-optical
constant (DIN 52314) K
|
4.0
10-6 mm2 N-1
|
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| Pressure
Resistance of DURAN Tubing and Capillary |
| Calculation
of pressure resistance (p) for a given Wall Thickness (WT) and a given
Outside Diameter (OD): |
|
|
OD
|
= |
Outside
Diameter in mm |
|
WT
|
= |
Wall Thickness
in mm |
|
p
|
= |
Pressure
Resistance in bar |
|
K
S
|
= |
Resistance
Parameter in N mm-2
|
|
| Calculation
of the Wall Thickness (WT) WT at a given pressure resistance (p) and
Outside Diameter (OD): |
|
| Resistance
parameter for DURAN Borosilicate Glass 3.3: K/S = 7 N mm-2
as per DIN EN ISO 1595 Standard Draft Pressure equipment made from
Borosilicate Glass 3.3: General rules for design, manufacture and
testing. Pressure resistance (p) is also impaired by the following:
|
-
Difference in temperature between inside and outside wall
- Surface Quality
- End Finish |
-
Observance of Conditions of Installation as per Pressure Vessel Regulations
-Tubing Length |
| Exact
calculations are available on request. |
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| Resistance
to Thermal Shock |
| According
to DIN ISO 718, the resistance to thermal shock is the difference
in temperature between the hot test sample and the cold water bath
(room temperature) at which 50% of all test samples show a tendency
to crack when quickly immersed. Resistance to thermal shock of tubing,
capillary and rod is dependent on the wall thickness, the shape and
size of the quenched area, the state of the surface, the stress which
may be present and the end finish. Fast, uneven heating or cooling
can easily lead to breakage as a result of tensile strength. It is
recommended not to exceed a temperature difference of 120°C. For
large wall thicknesses, this temperature is limited to lower values.
Listed below are some measured values to illustrate the resistance
to thermal shock of DURAN Borosilicate Glass 3.3 tubing and rod. These
should be used only as reference values as considerable differences
between tubing/rod of the same dimensions are possible. |
|
Tubing
|
OD 50.5/
WT 5.00 mm: 220°C
OD 133.0/ WT 7.00 mm: 180°C
OD 120.0/ WT 8.00 mm: 180°C
|
Rod
|
Diam.
24.0 mm: 140¡C
|
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| Chemical
Composition (main
components in approx. weight %) |
|
SIO2
|
B2O3
|
NA2O
+ K2O
|
AL2O3
|
|
81
|
13
|
4
|
2
|
Chemical
Data
| Hydrolytic
Class (ISO 719) |
1 |
| Acid Class
(ISO 1776) |
1 |
| Alkali Class
(ISO 695) |
2 |
DURAN Borosilicate Glass 3.3
is highly resistant to water, neutral and acid solutions, concentrated
acids and acid mixtures, and to chlorine, bromine, iodine and organic
substances. The chemical resistance of this glass is superior to that
of most metals and other materials, even when exposed to long processing
periods and temperatures above 100°C.
A slight release of mainly
monovalent ions takes place after exposure of the glass to water or acids.
A very thin layer of impervious silica gel is subsequently formed on the
surface of the glass which in turn slows down further attack. At higher
temperatures and in more concentrated forms the glass surface is subject
to increased attack by hydrofluoric acid, hot phosphoric acid and alkaline
solutions.
Transmission

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The excellent properties of
DURAN tubing, capillary and rod provide for good workability when forming
and cutting the glass with the normal techniques for technical glass.
To eliminate temporary stress as a result of the working process, the
glass should be well heated to a maximum temperature of 550 ¥C and kept
at this level for a maximum of 30 minutes; for a thinner wall only a fraction
of this period is necessary. In order not to affect the chemical stability
of the glass, annealing time should be kept as short as possible. We recommend
the annealing temperatures given in the table below:
Annealing
Schedule
| Wall Thickness
in mm |
Temperature
Range
|
|
550
to 480°C
|
480
to 400°C
|
400
to 20°C
|
| up to 3 |
12°C/min
|
24°C/min
|
up to
480°C/min
|
| up
to 6 |
3°C/min
|
6°C/min
|
up to
120°C/min
|
| up to 12 |
0.8°C/min
|
1.6°C/min
|
up to
32°C/min
|
If an article needs to be annealed
several times, the sum of all annealing periods at 550°C should not
exceed 2 hours. DURAN products can be fused stress-free with borosilicate
glasses of the same type and can be processed and annealed at the same
temperatures. Printing on DURAN tubing, capillary and rod can be done
with silver copper diffusion and screen-printing dyes.
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Technical
Terms of Supply
Specifications
|